Document Type

Article

Original Publication Date

2007

Journal/Book/Conference Title

Applied Physics Letters

Volume

91

Issue

6

DOI of Original Publication

10.1063/1.2768628

Comments

Originally published at http://dx.doi.org/10.1063/1.2768628

Date of Submission

April 2015

Abstract

A comprehensive theoretical study of electronic and magnetic properties of V-doped ZnO in bulk as well as (112¯0)thin films has been performed using density functional theory. Vanadium atoms substituted at Zn sites show very little selectivity of site occupancy. More importantly, different geometries with ferromagnetic, ferrimagnetic, and antiferromagnetic configurations are found to be energetically nearly degenerate both in Zn1−xVxO bulk and subsurface layers of the thin film. On the other hand, V atoms couple ferromagnetically when they occupy surface sites of the thin film. The diverse magnetic behaviors in V-doped ZnO account for the many reported conflicting experimental results.

Rights

Wang, Q., Sun, Q., Jena, P., et al. First-principles study of magnetic properties in V-doped ZnO. Applied Physics Letters, 91, 063116 (2007). Copyright © 2007 AIP Publishing LLC.

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