Document Type

Article

Original Publication Date

2012

Journal/Book/Conference Title

The Journal of Chemical Physics

Volume

137

Issue

16

DOI of Original Publication

10.1063/1.4763461

Comments

Originally published at https://dx.doi.org/10.1063/1.4763461

Date of Submission

October 2015

Abstract

Theoretical studies of the spin transport through a magnetic superatom dimer (Cs8V)-(Cs8V) have been carried out within a density functional theory combined with nonequilibrium Green's-function formalism. It is shown that the electronic transport is sensitive to the binding site as well as the contact distance between the dimer and the electrode, and that the conductance at zero bias exhibits an oscillatory behavior as a function of the contact distance. The conductance in ferromagnetic state shows an unusually high spin polarization that exceeds 80% at large separations. The IV curve shows negative differential resistance for specific contact distances, whose origin lies in the shift of frontier energy levels as well as the charged state of the superatom, under external bias.

Rights

Zhu, L., and Khanna, S. N. Quantum spin transport through magnetic superatom dimer (Cs8V-Cs8V). The Journal of Chemical Physics, 137, 164311 (2012). Copyright © 2012 American Institute of Physics.

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