Document Type

Article

Original Publication Date

2004

Journal/Book/Conference Title

Physical Review B

Volume

70

Issue

24

DOI of Original Publication

10.1103/PhysRevB.70.245411

Comments

Originally published by the American Physical Society at: http://dx.doi.org/10.1103/PhysRevB.70.245411

Date of Submission

May 2015

Abstract

First-principles calculations based on gradient corrected density functional theory show that a cluster of as few as 90 gold atoms can be stabilized in a ring structure having fcc (111) motif with the binding energy/atom and interatomic distance approaching 91% and 96% of the bulk values, respectively. Although the ring structure lies 0.139eV/atom higher in energy than a polyicosahedral structure, the calculated frequencies are real. Thus under appropriate experimental conditions it may still be possible to synthesize a metastable form of gold nanoring, as found in the recent experiment.

Rights

Sun, Q., Wang, Q., Jena, P. et al. Metastability of a gold nanoring: Density-functional calculations. Physical Review B, 70, 245411 (2004). Copyright © 2004 American Physical Society.

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